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Optically controlled polariton condensate molecules

Cherotchenko, ED
Sigurdsson, H
Askitopoulos, A
Nalitov, AV
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Abstract
A condensed-matter platform for analog simulation of complex two-dimensional molecular bonding configurations, based on optically trapped exciton-polariton condensates is proposed. The stable occupation of polariton condensates in the excited states of their optically configurable potential traps permits emulation of excited atomic orbitals. A classical mean-field model describing the dissipative coupling mechanism between p-orbital condensates is derived, identifying lowest-threshold condensation solutions as a function of trap parameters corresponding to bound and antibound π and σ bonding configurations, similar to those in quantum chemistry.
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Cherotchenko, E.D., Sigurdsson, H., Askitopoulos, A. and Nalitov, A.V. (2021) Optically controlled polariton condensate molecules. Physical Review B, 103, 115309.
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Journal article
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en
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This is an accepted manuscript of an article published by the American Physical Society in Physical Review B on 29/03/2021, available online: https://doi.org/10.1103/PhysRevB.103.115309 The accepted version of the publication may differ from the final published version.
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2469-9950
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2469-9969
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