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dc.contributor.authorKhan, Habib
dc.contributor.authorKaur, Sharanjit
dc.contributor.authorBaldwin, Timothy C
dc.contributor.authorRadecka, Iza
dc.contributor.authorJiang, Guozhan
dc.contributor.authorBretz, Inna
dc.contributor.authorDuale, Khadar
dc.contributor.authorAdamus, Grazyna
dc.contributor.authorKowalczuk, Marek
dc.date.accessioned2020-03-30T10:10:10Z
dc.date.available2020-03-30T10:10:10Z
dc.date.issued2020-03-19
dc.identifier.citationKhan, H., Kaur, S., Baldwin, T.C., Radecka, I., Jiang, G., Bretz, I., Duale, K., Adamus, G. and Kowalczuk, M. (2020) Effective control against broadleaf weed species provided by biodegradable PBAT/PLA mulch film embedded with the herbicide 2-methyl-4-chlorophenoxyacetic acid (MCPA), ACS Sustainable Chemistry & Engineering, 2020, https://doi.org/10.1021/acssuschemeng.0c00991en
dc.identifier.issn2168-0485en
dc.identifier.doi10.1021/acssuschemeng.0c00991en
dc.identifier.urihttp://hdl.handle.net/2436/623164
dc.descriptionThis is an accepted manuscript of an article published by American Chemical Society in ACS Sustainable Chemistry and Engineering on 19/03/2020, available online: https://doi.org/10.1021/acssuschemeng.0c00991 The accepted version of the publication may differ from the final published version.en
dc.description.abstractBiodegradable mulches are considered a promising alternative to polyethylene-based, nonbiodegradable mulch for sustainable agriculture. In the present study, a bioactive 2-methyl-4- cholorophenoxyacetic acid/poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (MCPA-PHBV) conjugate blended with biodegradable poly(butylene adipate-co-terephthalate/polylactide (PBAT/PLA) was developed and used as mulch under controlled condition greenhouse pot experiment with fava bean (Vicia faba) as the nontarget crop species. The objectives were to examine the effectiveness of sustained-release of MCPA herbicide from biodegradable mulch for broadleaf weed suppression and to assess any adverse effects of the herbicide on the nontarget species (fava bean). The energy-dispersive X-ray spectroscopy analysis (EDS) suggests that a substantial quantity of the herbicide was released from the biodegradable mulch which effectively killed the broadleaf weed species even at 1% MCPA concentration. However, the higher concentrations of the herbicide adversely affected several physiological parameters of fava bean growth and development. Stomatal conductance decreased, while leaf temperature subsequently rose (at MCPA concentrations 5, 7.5, and 10%). The quantum yield of the Photosystem II (PSII) indicates that the photosynthetic efficiency was also restricted at concentrations 7.5% and 10%. Evidently, this slow-release herbicide system worked efficiently for broadleaf weed control but at higher concentrations, resulted in adverse physiological effects on the nontarget crop species. This study has demonstrated that biodegradable mulches containing MCPA herbicide are able to effectively inhibit the growth of broad leaf weed species and may be of potential importance in a wide variety of horticultural and agricultural applications.en
dc.formatapplication/pdfen
dc.languageen
dc.language.isoenen
dc.publisherAmerican Chemical Society (ACS)en
dc.relation.urlhttps://pubs.acs.org/doi/10.1021/acssuschemeng.0c00991en
dc.subjectherbicide MCPA-PHBV conjugateen
dc.subjectbiodegradable PBAT/PLA blenden
dc.subjectbioactive mulch filmen
dc.subjectweed suppressionen
dc.subjectfava beanen
dc.subjectvicia fabaen
dc.titleEffective control against broadleaf weed species provided by biodegradable PBAT/PLA mulch film embedded with the herbicide 2-methyl-4-chlorophenoxyacetic acid (MCPA)en
dc.typeJournal articleen
dc.identifier.eissn2168-0485
dc.identifier.journalACS Sustainable Chemistry & Engineeringen
dc.date.updated2020-03-26T12:48:21Z
dc.date.accepted2020-03-10
rioxxterms.funderManolete Partners plcen
rioxxterms.identifier.projectUOW30032020IRen
rioxxterms.versionAMen
rioxxterms.licenseref.urihttps://creativecommons.org/licenses/by-nc-nd/4.0/en
rioxxterms.licenseref.startdate2021-03-19en
dc.description.versionPublished online
refterms.dateFCD2020-03-30T10:06:57Z
refterms.versionFCDAM


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