Bulking up: hexanuclear oximato Fe(III) complexes surrounded by sterically demanding co-ligands
dc.contributor.author | Houton, E | |
dc.contributor.author | Meally, ST | |
dc.contributor.author | Sanz, S | |
dc.contributor.author | Brechin, EK | |
dc.contributor.author | Jones, LF | |
dc.date.accessioned | 2020-01-24T15:23:14Z | |
dc.date.available | 2020-01-24T15:23:14Z | |
dc.date.issued | 2014-07-10 | |
dc.identifier.citation | Houton, E., Meally, S. T., Sanz, S., Brechin, E. K., Jones, L. F. (2014) Bulking up: hexanuclear oximato fe(iii) complexes surrounded by sterically demanding co-ligands. Inorganica Chimica Acta 421, pp. 416-422. | en |
dc.identifier.issn | 0020-1693 | en |
dc.identifier.doi | 10.1016/j.ica.2014.06.021 | en |
dc.identifier.uri | http://hdl.handle.net/2436/623020 | |
dc.description.abstract | Despite their inherent steric bulk, a combination of 2-hydroxy-1- naphthaldoxime (L1H2) with polyphenolic carboxylate ligands (1-Naphthoate, 9-Anthracene carboxylate) aid the construction and stabilisation of hexanuclear arrays of Fe(III) ions in the form of [Fe(III) 6O2(L1)2(O2C-R) 10(H2O)2]·8MeCN (R = Naphth-(C 10H8) (1); R = Anthra-(C14H9) (2)). Likewise, the sterically hindered ligand 3,5-di-tert-butyl-salicylaldoxime (L2H2) is able to aid the self-assembly of the tetranuclear, cubane-like species [Fe(III)4(L2) 4(MeOH)4(Cl)4] (3). Magnetic susceptibility studies carried out on 1 and 3 reveal antiferromagnetic exchange between the Fe(III) metal centres affording S = 0 ground spin states in both cases. © 2014 Elsevier B.V. All rights reserved. | en |
dc.description.sponsorship | Irish Research Council for Science and Technology (IRCSET Embark Program (EH) and the EPSRC. | en |
dc.format | application/pdf | en |
dc.language | en | |
dc.language.iso | en | en |
dc.publisher | Elsevier | en |
dc.relation.url | https://www.sciencedirect.com/science/article/pii/S0020169314003892?via%3Dihub | en |
dc.subject | Coordination chemistry | en |
dc.subject | Ferric cages | en |
dc.subject | Molecular magnetism | en |
dc.title | Bulking up: hexanuclear oximato Fe(III) complexes surrounded by sterically demanding co-ligands | en |
dc.type | Journal article | en |
dc.identifier.eissn | 1873-3255 | |
dc.identifier.journal | Inorganica Chimica Acta | en |
dc.date.updated | 2020-01-22T09:24:18Z | |
dc.date.accepted | 2014-06-13 | |
rioxxterms.funder | Kobayashi International Scholarship Foundation to S.A | en |
rioxxterms.identifier.project | UOW24012020LJ | en |
rioxxterms.version | AM | en |
rioxxterms.licenseref.uri | https://creativecommons.org/licenses/by-nc-nd/4.0/ | en |
rioxxterms.licenseref.startdate | 2020-01-24 | en |
dc.source.volume | 421 | |
dc.source.beginpage | 416 | |
dc.source.endpage | 422 | |
dc.description.version | Published version | |
refterms.dateFCD | 2020-01-24T15:23:01Z | |
refterms.versionFCD | AM | |
refterms.dateFOA | 2020-01-24T15:23:15Z |