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dc.contributor.authorHouton, E
dc.contributor.authorMeally, ST
dc.contributor.authorSanz, S
dc.contributor.authorBrechin, EK
dc.contributor.authorJones, LF
dc.date.accessioned2020-01-24T15:23:14Z
dc.date.available2020-01-24T15:23:14Z
dc.date.issued2014-07-10
dc.identifier.citationHouton, E., Meally, S. T., Sanz, S., Brechin, E. K., Jones, L. F. (2014) Bulking up: hexanuclear oximato fe(iii) complexes surrounded by sterically demanding co-ligands. Inorganica Chimica Acta 421, pp. 416-422.en
dc.identifier.issn0020-1693en
dc.identifier.doi10.1016/j.ica.2014.06.021en
dc.identifier.urihttp://hdl.handle.net/2436/623020
dc.description.abstractDespite their inherent steric bulk, a combination of 2-hydroxy-1- naphthaldoxime (L1H2) with polyphenolic carboxylate ligands (1-Naphthoate, 9-Anthracene carboxylate) aid the construction and stabilisation of hexanuclear arrays of Fe(III) ions in the form of [Fe(III) 6O2(L1)2(O2C-R) 10(H2O)2]·8MeCN (R = Naphth-(C 10H8) (1); R = Anthra-(C14H9) (2)). Likewise, the sterically hindered ligand 3,5-di-tert-butyl-salicylaldoxime (L2H2) is able to aid the self-assembly of the tetranuclear, cubane-like species [Fe(III)4(L2) 4(MeOH)4(Cl)4] (3). Magnetic susceptibility studies carried out on 1 and 3 reveal antiferromagnetic exchange between the Fe(III) metal centres affording S = 0 ground spin states in both cases. © 2014 Elsevier B.V. All rights reserved.en
dc.description.sponsorshipIrish Research Council for Science and Technology (IRCSET Embark Program (EH) and the EPSRC.en
dc.formatapplication/pdfen
dc.languageen
dc.language.isoenen
dc.publisherElsevieren
dc.relation.urlhttps://www.sciencedirect.com/science/article/pii/S0020169314003892?via%3Dihuben
dc.subjectCoordination chemistryen
dc.subjectFerric cagesen
dc.subjectMolecular magnetismen
dc.titleBulking up: hexanuclear oximato Fe(III) complexes surrounded by sterically demanding co-ligandsen
dc.typeJournal articleen
dc.identifier.eissn1873-3255
dc.identifier.journalInorganica Chimica Actaen
dc.date.updated2020-01-22T09:24:18Z
dc.date.accepted2014-06-13
rioxxterms.funderKobayashi International Scholarship Foundation to S.Aen
rioxxterms.identifier.projectUOW24012020LJen
rioxxterms.versionAMen
rioxxterms.licenseref.urihttps://creativecommons.org/licenses/by-nc-nd/4.0/en
rioxxterms.licenseref.startdate2020-01-24en
dc.source.volume421
dc.source.beginpage416
dc.source.endpage422
dc.description.versionPublished version
refterms.dateFCD2020-01-24T15:23:01Z
refterms.versionFCDAM
refterms.dateFOA2020-01-24T15:23:15Z


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