Show simple item record

dc.contributor.authorSlater-Parry, ME
dc.contributor.authorDurrant, JP
dc.contributor.authorHowells, JM
dc.contributor.authorPitak, MB
dc.contributor.authorHorton, PN
dc.contributor.authorKlooster, WT
dc.contributor.authorColes, SJ
dc.contributor.authorO'Connor, HM
dc.contributor.authorBrechin, EK
dc.contributor.authorBarra, AL
dc.contributor.authorJones, LF
dc.date.accessioned2020-01-23T12:57:32Z
dc.date.available2020-01-23T12:57:32Z
dc.date.issued2018-12-20
dc.identifier.citationSlater-Parry, M. E., Durrant, J. P., Howells, J. M., Pitak, M. B., Horton, P. N., Klooster, W. T., Coles, S. J., O'Connor, H. M., Brechin, E. K., Barra, A-L & Jones, L. F. (2019) Crowding out: ligand modifications and their structure directing effects on brucite-like {M-x((3)-OH)(y)} (M = Co(ii), Ni(ii)) core growth within polymetallic cages, Dalton Transactions, 48(4), pp. 1477-1488. https://doi.org/10.1039/C8DT04229Ben
dc.identifier.issn1477-9226en
dc.identifier.pmid30632582
dc.identifier.doi10.1039/c8dt04229ben
dc.identifier.urihttp://hdl.handle.net/2436/623018
dc.descriptionThis is an accepted manuscript of an article published by Royal Society of Chemistry in Dalton Transactions on 20/12/2018, available online: https://doi.org/10.1039/C8DT04229B The accepted version of the publication may differ from the final published version.
dc.description.abstract© The Royal Society of Chemistry. Previous employment of the ligands 2-methoxy-6-[(methylimino)methyl]phenol (L 1 H) and 2-methoxy-6-[(phenylimino)methyl]phenol (L 2 H) has resulted in the self-assembly of pseudo metallocalix[6]arene complexes of general formulae: [M 7 (μ 3 -OH) 6 (L x ) 6 ](NO 3 ) y (M = Ni(ii), x = 1, y = 2 (1) and Co(ii/iii), x = 2, y = 3 (2)). Extrapolating upon this work, we report the coordination chemistry of ligands 2-methoxy-6-{[(2-methoxyphenyl)imino]methyl}phenol (L 3 H), 2-[(benzylimino)methyl]-6-methoxyphenol (L 4 H), 2-[(benzylamino)methyl]-6-methoxyphenol (L 5 H) and 2-[(benzylamino)methyl]-4-bromo-6-methoxyphenol (L 6 H), whose structures are modifications of ligands L 1-2 H. These ligands are employed in the synthesis and characterisation of the dimetallic complex [Ni(ii) 2 (L 3 ) 3 (H 2 O)](NO 3 )·2H 2 O·3MeOH (3); the monometallic complexes [Ni(ii)(L 4 ) 2 ] (4) and [Co(iii)(L 4 ) 3 ]·H 2 O·MeOH (5a); and the tetranuclear pseudo metallocalix[4]arene complexes: [(NO 3 )⊂Co(ii) 4 (μ 3 -OH) 2 (L 5 ) 4 (H 2 O) 2 ](NO 3 )·H 2 O (6), [(NO 3 )⊂Ni(ii) 4 (μ 3 -OH) 2 (L 5 ) 4 (H 2 O) 2 ](NO 3 )·H 2 O (7) and [Ni(ii) 4 (μ 3 -OH) 2 (L 6 ) 4 (NO 3 ) 2 ]·MeCN (8). The tetrametallic 'butterfly' core topologies in 6-8 are discussed with respect to their structural and topological relationship with their heptanuclear [M 7 ] (M = Co(ii), Ni(ii)) pseudo metallocalix[6]arene ancestors (1 and 2).en
dc.formatapplication/pdfen
dc.languageeng
dc.language.isoenen
dc.publisherRoyal Society of Chemistry (RSC)en
dc.relation.urlhttps://pubs.rsc.org/en/content/articlelanding/2019/DT/C8DT04229B#!divAbstracten
dc.titleCrowding out: ligand modifications and their structure directing effects on brucite-like {Mx(μ3-OH)y} (M = Co(ii), Ni(ii)) core growth within polymetallic cagesen
dc.typeJournal articleen
dc.identifier.eissn1477-9234
dc.identifier.journalDalton Transactionsen
dc.date.updated2020-01-22T08:39:54Z
dc.contributor.institutionSchool of Natural Sciences, Bangor University, Bangor, Wales, LL57 2DG, UK. leigh.jones@bangor.ac.uk.
pubs.place-of-publicationEngland
dc.date.accepted2018-12-20
rioxxterms.funderEngineering and Physical Sciences Research Councilen
rioxxterms.identifier.projectEP/N01331X/1en
rioxxterms.versionAMen
rioxxterms.licenseref.urihttps://creativecommons.org/licenses/by-nc/4.0/en
rioxxterms.licenseref.startdate2020-01-23en
dc.source.volume48
dc.source.issue4
dc.source.beginpage1477
dc.source.endpage1488
dc.description.versionPublished version
refterms.dateFCD2020-01-23T12:42:14Z
refterms.versionFCDAM
refterms.dateFOA2020-01-23T12:57:33Z


Files in this item

Thumbnail
Name:
SlaterParry_et_al_Crowding_out ...
Size:
1.223Mb
Format:
PDF

This item appears in the following Collection(s)

Show simple item record

https://creativecommons.org/licenses/by-nc/4.0/
Except where otherwise noted, this item's license is described as https://creativecommons.org/licenses/by-nc/4.0/