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dc.contributor.authorFugu, MB
dc.contributor.authorEllaby, RJ
dc.contributor.authorO'Connor, HM
dc.contributor.authorPitak, MB
dc.contributor.authorKlooster, W
dc.contributor.authorHorton, PN
dc.contributor.authorColes, SJ
dc.contributor.authorAl-Mashhadani, MH
dc.contributor.authorPerepichka, IF
dc.contributor.authorBrechin, EK
dc.contributor.authorJones, LF
dc.date.accessioned2020-01-23T12:31:48Z
dc.date.available2020-01-23T12:31:48Z
dc.date.issued2019-06-04
dc.identifier.citationFugu, M. B., Ellaby, R. J., O'Connor, H. M., Pitak, M. B., Klooster, W., Horton, P. N., Coles, S. J., Al-Mashhadani, M. H., Brechin, E. K., Perepichka, I. and Jones, L. F. (2019) Mono- and ditopic hydroxamate ligands towards discrete and extended network architectures, Dalton Transactions, no. 27, pp. , 10180–10190. https://doi.org/10.1039/C9DT01531Ken
dc.identifier.issn1477-9226en
dc.identifier.pmid31187830
dc.identifier.doi10.1039/c9dt01531ken
dc.identifier.urihttp://hdl.handle.net/2436/623017
dc.description.abstract© 2019 The Royal Society of Chemistry. A family of mono- and ditopic hydroxamic acids has been employed in the synthesis and structural and physical characterisation of discrete (0D) and (1- and 2-D) extended network coordination complexes. Examples of the latter include the 1-D coordination polymer {[Zn(ii)(L3H)2]·2MeOH}n (5; L3H2 = 2-(methylamino)phenylhydroxamic acid) and the 2-D extended network {[Cu(ii)(L2H)(H2O)(NO3)]·H2O}n (5; L2H2 = 4-amino-2-(acetoxy)phenylhydroxamic acid). The 12-MC-4 metallacrown [Cu(ii)5(L4H)4(MeOH)2(NO3)2]·3H2O·4MeOH (7) represents the first metal complex constructed using the novel ligand N-hydroxy-2-[(2-hydroxy-3-methoxybenzyl)amino]benzamide (L4H3). Variable temperature magnetic susceptibility studies confirm strong antiferromagnetic exchange between the Cu(ii) centres in 7. Coordination polymer 5 shows photoluminescence in the blue region (λPL ∼ 421-450 nm) with a bathochromic shift of the emission (∼15-30 nm) from solution to the solid state.en
dc.description.sponsorshipSchool of Natural Sciences at Bangor University (LFJ, RE and BFM). Overseas fellowship awarded to BFM by the University of Maiduguri and the Petroleum Technology Development Fund (PTDF). EKB thanks the EPSRC (EP/N01331X/1, EP/P025986/1) for support.en
dc.formatapplication/pdfen
dc.languageeng
dc.language.isoenen
dc.publisherRoyal Society of Chemistry (RSC)en
dc.relation.urlhttps://pubs.rsc.org/en/content/articlelanding/2019/DT/C9DT01531K#!divAbstracten
dc.titleMono- and ditopic hydroxamate ligands towards discrete and extended network architecturesen
dc.typeJournal articleen
dc.identifier.eissn1477-9234
dc.identifier.journalDalton Transactionsen
dc.date.updated2020-01-22T08:39:19Z
dc.contributor.institutionSchool of Natural Sciences, Bangor University, Bangor, Wales LL57 2DG, UK. leigh.jones@bangor.ac.uk.
pubs.place-of-publicationEngland
dc.date.accepted2019-06-04
rioxxterms.funderUniversity of Maiduguri and the Petroleum Technology Development Fund/ EPSRCen
rioxxterms.identifier.projectEP/N01331X/1en
rioxxterms.identifier.projectEP/P025986/1en
rioxxterms.versionAMen
rioxxterms.licenseref.urihttps://creativecommons.org/licenses/by-nc-nd/4.0/en
rioxxterms.licenseref.startdate2020-06-04en
dc.source.volume48
dc.source.issue27
dc.source.beginpage10180
dc.source.endpage10190
dc.description.versionPublished version
refterms.dateFCD2020-01-23T12:31:07Z
refterms.versionFCDAM


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