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dc.contributor.authorGhosh, S.
dc.contributor.authorNixon, K.L.
dc.contributor.authorPires, W.A.D.
dc.contributor.authorAmorim, R.A.A.
dc.contributor.authorNeves, R.F.C.
dc.contributor.authorDuque, H.V.
dc.contributor.authorda Silva, D.G.M.
dc.contributor.authorJones, D.B.
dc.contributor.authorBlanco, F.
dc.contributor.authorGarcia, G.
dc.contributor.authorBrunger, M.J.
dc.contributor.authorLopes, M.C.A.
dc.date.accessioned2018-06-05T15:15:31Z
dc.date.available2018-06-05T15:15:31Z
dc.date.issued2018-04-10
dc.identifier.citation(2018) 'Electron impact ionization of 1-butanol: II. Total ionization cross sections and appearance energies', International Journal of Mass Spectrometry, 430:44
dc.identifier.issn1387-3806
dc.identifier.doi10.1016/j.ijms.2018.03.012
dc.identifier.urihttp://hdl.handle.net/2436/621330
dc.description.abstractExperimental and theoretical data on total ionization cross sections for electron scattering by 1-butanol molecules in the energy range 10–100 eV are reported in this work. The experimental data were obtained from the addition of partial ionization cross sections (PICS) of 38 cationic fragments registered using a Hiden Analytical quadrupole mass spectrometer (EPIC 300), which are reported in a companion paper (Pires et al., 2018). The theoretical data were generated using the Binary-Encounter-Bethe and independent atom model plus screening corrected additivity rule approaches. Additionally, we also report the appearance energies (AEs) and Wannier exponents for 36 of the 38 main cationic fragments observed in our experiments. Our experimental TICS data are typically found to be in good agreement with our theoretical results, and with other experimental and theoretical TICS data of 1-butanol currently available in the literature. Agreement of our AEs and the previous data, again where a comparison is possible, is also found to be satisfactory.
dc.formatapplication/PDF
dc.language.isoen
dc.publisherElsevier
dc.relation.urlhttp://linkinghub.elsevier.com/retrieve/pii/S1387380618300538
dc.subjectMass spectra
dc.subjectDirect ionization and dissociative ionization
dc.subjectPartial ionization cross sections
dc.titleElectron impact ionization of 1-butanol: II. Total ionization cross sections and appearance energies
dc.typeJournal article
dc.identifier.journalInternational Journal of Mass Spectrometry
dc.date.accepted2018-03-29
rioxxterms.funderUniversity of Wolverhampton
rioxxterms.identifier.projectUOW05062018KN1
rioxxterms.versionAM
rioxxterms.licenseref.urihttps://creativecommons.org/licenses/by-nc-nd/4.0/
rioxxterms.licenseref.startdate2020-11-11
dc.source.volume430
dc.source.beginpage44
dc.source.endpage51
refterms.dateFCD2018-10-19T09:26:31Z
refterms.versionFCDAM
html.description.abstractExperimental and theoretical data on total ionization cross sections for electron scattering by 1-butanol molecules in the energy range 10–100 eV are reported in this work. The experimental data were obtained from the addition of partial ionization cross sections (PICS) of 38 cationic fragments registered using a Hiden Analytical quadrupole mass spectrometer (EPIC 300), which are reported in a companion paper (Pires et al., 2018). The theoretical data were generated using the Binary-Encounter-Bethe and independent atom model plus screening corrected additivity rule approaches. Additionally, we also report the appearance energies (AEs) and Wannier exponents for 36 of the 38 main cationic fragments observed in our experiments. Our experimental TICS data are typically found to be in good agreement with our theoretical results, and with other experimental and theoretical TICS data of 1-butanol currently available in the literature. Agreement of our AEs and the previous data, again where a comparison is possible, is also found to be satisfactory.


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