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dc.contributor.authorFarzaneh, Farzin
dc.contributor.authorZamanifar, Elham
dc.contributor.authorWilliams, Craig D.
dc.date.accessioned2008-06-25T13:31:12Z
dc.date.available2008-06-25T13:31:12Z
dc.date.issued2004
dc.identifier.citationJournal of Molecular Catalysis A: Chemical, 218(2): 203-209
dc.identifier.issn1381-1169
dc.identifier.doi10.1016/j.molcata.2004.03.046
dc.identifier.urihttp://hdl.handle.net/2436/30459
dc.description.abstractVanadium containing MCM-41(V-MCM-41) was synthesized by one pot synthesis and characterized by spectroscopic techniques. The oxidation of olefins such as 1-hexene, cyclohexene, cyclopentene, norbornene and trans-2-hexene-1-ol with tertiary butyl hydroperoxide (TBHP) in the presence of V-MCM-41 as catalyst in different solvents(CH2Cl2, CH3CN, CH3OH·CHCl3) is described. It was found that V-MCM-41 in refluxing CHCl3 was very reactive for epoxidation of trans-2-hexene-1-ol with 52% reactivity and 100% selectivity. Oxidation of trans-2-hexene-1-ol to the corresponding epoxide in the absence of solvent was successfully carried out with the enhancement of reactivity to 94%.
dc.language.isoen
dc.publisherAmsterdam: Elsevier
dc.relation.urlhttp://www.sciencedirect.com/science?_ob=ArticleURL&_udi=B6TGM-4CG0SSP-2&_user=1644469&_rdoc=1&_fmt=&_orig=search&_sort=d&view=c&_acct=C000054077&_version=1&_urlVersion=0&_userid=1644469&md5=c4c4dcde0919de9c5ddbd9f0631a7b56
dc.subjectV-MCM-41
dc.subjectEpoxidation
dc.subjectOlefins
dc.subjectTrans-2-Hexene-1-ol
dc.subjectChemistry, Organic
dc.subjectCatalysis
dc.subjectGeochemistry
dc.subjectZeolites
dc.titleV-MCM-41 as selective catalyst for epoxidation of olefins and trans-2-hexene-1-ol.
dc.typeJournal article
dc.identifier.journalJournal of Molecular Catalysis A: Chemical
html.description.abstractVanadium containing MCM-41(V-MCM-41) was synthesized by one pot synthesis and characterized by spectroscopic techniques. The oxidation of olefins such as 1-hexene, cyclohexene, cyclopentene, norbornene and trans-2-hexene-1-ol with tertiary butyl hydroperoxide (TBHP) in the presence of V-MCM-41 as catalyst in different solvents(CH2Cl2, CH3CN, CH3OH·CHCl3) is described. It was found that V-MCM-41 in refluxing CHCl3 was very reactive for epoxidation of trans-2-hexene-1-ol with 52% reactivity and 100% selectivity. Oxidation of trans-2-hexene-1-ol to the corresponding epoxide in the absence of solvent was successfully carried out with the enhancement of reactivity to 94%.


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