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    V-MCM-41 as selective catalyst for epoxidation of olefins and trans-2-hexene-1-ol.

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    Authors
    Farzaneh, Farzin
    Zamanifar, Elham
    Williams, Craig D.
    Issue Date
    2004
    
    Metadata
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    Abstract
    Vanadium containing MCM-41(V-MCM-41) was synthesized by one pot synthesis and characterized by spectroscopic techniques. The oxidation of olefins such as 1-hexene, cyclohexene, cyclopentene, norbornene and trans-2-hexene-1-ol with tertiary butyl hydroperoxide (TBHP) in the presence of V-MCM-41 as catalyst in different solvents(CH2Cl2, CH3CN, CH3OH·CHCl3) is described. It was found that V-MCM-41 in refluxing CHCl3 was very reactive for epoxidation of trans-2-hexene-1-ol with 52% reactivity and 100% selectivity. Oxidation of trans-2-hexene-1-ol to the corresponding epoxide in the absence of solvent was successfully carried out with the enhancement of reactivity to 94%.
    Citation
    Journal of Molecular Catalysis A: Chemical, 218(2): 203-209
    Publisher
    Amsterdam: Elsevier
    Journal
    Journal of Molecular Catalysis A: Chemical
    URI
    http://hdl.handle.net/2436/30459
    DOI
    10.1016/j.molcata.2004.03.046
    Additional Links
    http://www.sciencedirect.com/science?_ob=ArticleURL&_udi=B6TGM-4CG0SSP-2&_user=1644469&_rdoc=1&_fmt=&_orig=search&_sort=d&view=c&_acct=C000054077&_version=1&_urlVersion=0&_userid=1644469&md5=c4c4dcde0919de9c5ddbd9f0631a7b56
    Type
    Journal article
    Language
    en
    ISSN
    1381-1169
    ae974a485f413a2113503eed53cd6c53
    10.1016/j.molcata.2004.03.046
    Scopus Count
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    Faculty of Science and Engineering

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