2.50
Hdl Handle:
http://hdl.handle.net/2436/608507
Title:
Thermal energy storage using metal–organic framework materials
Authors:
Elsayed, Ahmed; Elsayed, Eman; AL-Dadah, Raya; Mahmoud, Saad; Elshaer, Amr; Kaialy, Waseem
Abstract:
Metal–organic framework (MOF) materials are new adsorbent materials that have high surface area and pore volume and hence high adsorption uptake. The previous exceptional properties make this class of materials have a great potential in many applications like cooling, gas separation and energy storage. However, there is very limited information on the performance of metal–organic framework materials in energy storage applications and their performance compared to conventional adsorbents. This paper aims to present an experimental characterisation of CPO-27(Ni) MOF material for water adsorption and to investigate its viability for energy storage. CPO-27(Ni) (known as MOF-74(Ni)), which is a MOF material that has high water adsorption capabilities of 0.47 gH2O gads−1 and hydrothermally stable and can be supplied in large quantities. Firstly, the material water adsorption isotherms were predicated using Materials Studio software via the material structure information and then compared to the experimentally measured isotherms. The experimentally measured isotherms and kinetics were used to model a double bed adsorption system for energy storage application using Simulink–Matlab software coupled with Nist RefProp thermophysical routines. Finally, the performance of CPO-27(Ni) was then compared with silica gel. The CPO-27(Ni) was found to outperform silica gel at long half cycle time (more than 30 min) at low evaporating temperature making it suitable for energy storage applications. The energy stored in the condenser and the adsorption bed was found to be dependent mostly on the regeneration and the cooling temperatures. The potential of the energy recovered from the adsorption bed can be double the one recovered from the condenser. Also, the energy recovery during condensation and adsorption was found to be independent of the reactor conductance except at small conductance ratio. Finally, the adsorption unit cooling water flow strategy was found to affect the amount of the energy recovered as recirculating the cooling water through the adsorption bed and then condenser was found to decrease the recovered energy from the condenser by 4%.
Citation:
Thermal energy storage using metal–organic framework materials 2016 Applied Energy
Publisher:
Applied Energy
Journal:
Applied Energy
Issue Date:
5-Apr-2016
URI:
http://hdl.handle.net/2436/608507
DOI:
10.1016/j.apenergy.2016.03.113
Additional Links:
http://linkinghub.elsevier.com/retrieve/pii/S0306261916304342
Type:
Article
Language:
en
Appears in Collections:
Pharmacy and Natural Products Research Group

Full metadata record

DC FieldValue Language
dc.contributor.authorElsayed, Ahmeden
dc.contributor.authorElsayed, Emanen
dc.contributor.authorAL-Dadah, Rayaen
dc.contributor.authorMahmoud, Saaden
dc.contributor.authorElshaer, Amren
dc.contributor.authorKaialy, Waseemen
dc.date.accessioned2016-05-06T13:49:08Zen
dc.date.available2016-05-06T13:49:08Zen
dc.date.issued2016-04-05en
dc.identifier.citationThermal energy storage using metal–organic framework materials 2016 Applied Energyen
dc.identifier.doi10.1016/j.apenergy.2016.03.113en
dc.identifier.urihttp://hdl.handle.net/2436/608507en
dc.description.abstractMetal–organic framework (MOF) materials are new adsorbent materials that have high surface area and pore volume and hence high adsorption uptake. The previous exceptional properties make this class of materials have a great potential in many applications like cooling, gas separation and energy storage. However, there is very limited information on the performance of metal–organic framework materials in energy storage applications and their performance compared to conventional adsorbents. This paper aims to present an experimental characterisation of CPO-27(Ni) MOF material for water adsorption and to investigate its viability for energy storage. CPO-27(Ni) (known as MOF-74(Ni)), which is a MOF material that has high water adsorption capabilities of 0.47 gH2O gads−1 and hydrothermally stable and can be supplied in large quantities. Firstly, the material water adsorption isotherms were predicated using Materials Studio software via the material structure information and then compared to the experimentally measured isotherms. The experimentally measured isotherms and kinetics were used to model a double bed adsorption system for energy storage application using Simulink–Matlab software coupled with Nist RefProp thermophysical routines. Finally, the performance of CPO-27(Ni) was then compared with silica gel. The CPO-27(Ni) was found to outperform silica gel at long half cycle time (more than 30 min) at low evaporating temperature making it suitable for energy storage applications. The energy stored in the condenser and the adsorption bed was found to be dependent mostly on the regeneration and the cooling temperatures. The potential of the energy recovered from the adsorption bed can be double the one recovered from the condenser. Also, the energy recovery during condensation and adsorption was found to be independent of the reactor conductance except at small conductance ratio. Finally, the adsorption unit cooling water flow strategy was found to affect the amount of the energy recovered as recirculating the cooling water through the adsorption bed and then condenser was found to decrease the recovered energy from the condenser by 4%.en
dc.language.isoenen
dc.publisherApplied Energyen
dc.relation.urlhttp://linkinghub.elsevier.com/retrieve/pii/S0306261916304342en
dc.rightsArchived with thanks to Applied Energyen
dc.titleThermal energy storage using metal–organic framework materialsen
dc.typeArticleen
dc.identifier.journalApplied Energyen
rioxxterms.versionAOen
This item is licensed under a Creative Commons License
Creative Commons
All Items in WIRE are protected by copyright, with all rights reserved, unless otherwise indicated.