2.50
Hdl Handle:
http://hdl.handle.net/2436/30459
Title:
V-MCM-41 as selective catalyst for epoxidation of olefins and trans-2-hexene-1-ol.
Authors:
Farzaneh, Farzin; Zamanifar, Elham; Williams, Craig D.
Abstract:
Vanadium containing MCM-41(V-MCM-41) was synthesized by one pot synthesis and characterized by spectroscopic techniques. The oxidation of olefins such as 1-hexene, cyclohexene, cyclopentene, norbornene and trans-2-hexene-1-ol with tertiary butyl hydroperoxide (TBHP) in the presence of V-MCM-41 as catalyst in different solvents(CH2Cl2, CH3CN, CH3OH·CHCl3) is described. It was found that V-MCM-41 in refluxing CHCl3 was very reactive for epoxidation of trans-2-hexene-1-ol with 52% reactivity and 100% selectivity. Oxidation of trans-2-hexene-1-ol to the corresponding epoxide in the absence of solvent was successfully carried out with the enhancement of reactivity to 94%.
Citation:
Journal of Molecular Catalysis A: Chemical, 218(2): 203-209
Publisher:
Amsterdam: Elsevier
Journal:
Journal of Molecular Catalysis A: Chemical
Issue Date:
2004
URI:
http://hdl.handle.net/2436/30459
DOI:
10.1016/j.molcata.2004.03.046
Additional Links:
http://www.sciencedirect.com/science?_ob=ArticleURL&_udi=B6TGM-4CG0SSP-2&_user=1644469&_rdoc=1&_fmt=&_orig=search&_sort=d&view=c&_acct=C000054077&_version=1&_urlVersion=0&_userid=1644469&md5=c4c4dcde0919de9c5ddbd9f0631a7b56
Type:
Article
Language:
en
ISSN:
1381-1169
Appears in Collections:
Plant and Environmental Research Group

Full metadata record

DC FieldValue Language
dc.contributor.authorFarzaneh, Farzin-
dc.contributor.authorZamanifar, Elham-
dc.contributor.authorWilliams, Craig D.-
dc.date.accessioned2008-06-25T13:31:12Z-
dc.date.available2008-06-25T13:31:12Z-
dc.date.issued2004-
dc.identifier.citationJournal of Molecular Catalysis A: Chemical, 218(2): 203-209en
dc.identifier.issn1381-1169-
dc.identifier.doi10.1016/j.molcata.2004.03.046-
dc.identifier.urihttp://hdl.handle.net/2436/30459-
dc.description.abstractVanadium containing MCM-41(V-MCM-41) was synthesized by one pot synthesis and characterized by spectroscopic techniques. The oxidation of olefins such as 1-hexene, cyclohexene, cyclopentene, norbornene and trans-2-hexene-1-ol with tertiary butyl hydroperoxide (TBHP) in the presence of V-MCM-41 as catalyst in different solvents(CH2Cl2, CH3CN, CH3OH·CHCl3) is described. It was found that V-MCM-41 in refluxing CHCl3 was very reactive for epoxidation of trans-2-hexene-1-ol with 52% reactivity and 100% selectivity. Oxidation of trans-2-hexene-1-ol to the corresponding epoxide in the absence of solvent was successfully carried out with the enhancement of reactivity to 94%.en
dc.language.isoenen
dc.publisherAmsterdam: Elsevieren
dc.relation.urlhttp://www.sciencedirect.com/science?_ob=ArticleURL&_udi=B6TGM-4CG0SSP-2&_user=1644469&_rdoc=1&_fmt=&_orig=search&_sort=d&view=c&_acct=C000054077&_version=1&_urlVersion=0&_userid=1644469&md5=c4c4dcde0919de9c5ddbd9f0631a7b56en
dc.subjectV-MCM-41en
dc.subjectEpoxidationen
dc.subjectOlefinsen
dc.subjectTrans-2-Hexene-1-olen
dc.subjectChemistry, Organicen
dc.subjectCatalysisen
dc.subjectGeochemistryen
dc.subjectZeolitesen
dc.titleV-MCM-41 as selective catalyst for epoxidation of olefins and trans-2-hexene-1-ol.en
dc.typeArticleen
dc.identifier.journalJournal of Molecular Catalysis A: Chemicalen
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